I. r. spectroscopic evidence, including 2H labeling, is presented to show that photolysis of [(η6C6R6)M(CO)2] complexes (M = Rh, R = Me; M = Ir, R = H, Me) in CH4 matrices at 12 K leads primarily to [(η6-C6R6)M(CO)(H)(Me)] species whereas in Ar and N2 matrices only small yields of [(η5-C5R5)M(CO)] species are observed.
A. J. Rest, I. Whitwell, W. A. G. Graham, J. K. Hoyano and A. D. McMaster, J. Chem. Soc., Chem. Commun., 1984, 624 DOI: 10.1039/C39840000624
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