Issue 9, 1984

Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me3Si)2C(Ag)C5H4N}2], a dimeric compound void of electron-deficient bonding

Abstract

The silver (I) alkyl complex [{2-(Me3Si)2C(Ag)C5H4N}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5)Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5)Å; the Ag ⋯ Ag′ separation is 2.654 (1)Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 612-613

Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me3Si)2C(Ag)C5H4N}2], a dimeric compound void of electron-deficient bonding

R. I. Papasergio, C. L. Raston and A. H. White, J. Chem. Soc., Chem. Commun., 1984, 612 DOI: 10.1039/C39840000612

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