Issue 9, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Allylsilane cyclisations in organic synthesis; formation of a cyclopentane via cyclisation of an epoxy-allylsilane

Thuan Siah Tan,   Andrew N. Mather,   Garry Procter  and  Alan H. Davidson  

Abstract

The epoxy-allylsilane (1) was prepared by two routes and cyclised stereoselectively to give the cis-cyclopentane (9) on treatment with TiCl4; equilibration of the aldehyde corresponding to (9) gave the trans-isomer in high yield.

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Article information

DOI
https://doi.org/10.1039/C39840000585
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 585-586

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Allylsilane cyclisations in organic synthesis; formation of a cyclopentane via cyclisation of an epoxy-allylsilane

T. S. Tan, A. N. Mather, G. Procter and A. H. Davidson, J. Chem. Soc., Chem. Commun., 1984, 585 DOI: 10.1039/C39840000585

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