The linear polymethanoaromatic compounds, (2a–c), (4a), (5a), and (6) have been synthesized and their photoelectron spectra measured, which revealed the presence of large π orbital interactions through bonds, for (2b,c), and laticyclic hyperconjugative interactions in (4a).
M. N. Paddon-Row, H. K. Patney, J. B. Peel and G. D. Willett, J. Chem. Soc., Chem. Commun., 1984, 564 DOI: 10.1039/C39840000564
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