The synthesis of 1,4,5,7-teetraoxygenated naphthalenes is described, as well as their selective acylation at either C-3 or C-8 using either trifluoroacetic anhydride or acetic acid and trifluoroacetic anhydride; the potential of these reactions in the synthesis of naturally occurring naphthoquinones is referred to.
R. G. F. Giles, S. C. Yorke, I. R. Green and V. I. Hugo, J. Chem. Soc., Chem. Commun., 1984, 554 DOI: 10.1039/C39840000554
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