The 9,10-ethylene linked flavin (1) is more reactive than the 9, 10-trimethylene linked flavin (2) for oxidation (Fox.→ FH2), and less reactive to reduction[FH2→ Fox. and FH2→·FM (metal-chelated flavin radical)], evidence that ·FM contains an almost planar flavin moiety.
Y. Yano, M. Nakazato and K. Kasagawa, J. Chem. Soc., Chem. Commun., 1984, 498 DOI: 10.1039/C39840000498
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