The synthesis of the alkaloid swainsonine is described starting from methyl 3-amino-3-deoxy-α-D-mannopyranoside hydrochloride (readily available from D-glucose) in which all the chiral centers of the aminohexose are incorporated intact into the alkaloid.
M. H. Ali, L. Hough and A. C. Richardson, J. Chem. Soc., Chem. Commun., 1984, 447 DOI: 10.1039/C39840000447
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