Issue 7, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Coupling of ethylidyne and carnbonyl ligands leading to a µ3η2 bonded propynolate anion induced by one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4]: X-ray crystal structure of [Fe3(CO)9(µ3, µ2-MeC[triple bond, length half m-dash]CO)][PPh4]2

Françoise Dahan  and  René Mathieu  

Abstract

The electrochemical one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4] leads to a product containing a µ3,η2 bonded propynolate anion, [Fe3(CO)9(µ3, η2-MeC[triple bond, length half m-dash]CO)][PPh4]2.

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Article information

DOI
https://doi.org/10.1039/C39840000432
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 432-433

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Coupling of ethylidyne and carnbonyl ligands leading to a µ3η2 bonded propynolate anion induced by one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4]: X-ray crystal structure of [Fe3(CO)9(µ3, µ2-MeC[triple bond, length half m-dash]CO)][PPh4]2

F. Dahan and R. Mathieu, J. Chem. Soc., Chem. Commun., 1984, 432 DOI: 10.1039/C39840000432

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