The increased kinetic acidity of benzylic hydrogen atoms of aromatic steroids temporarily modified by the Cr(CO)3 group provides access to 6-alkylated oestradiol derivatives with controlled stereochemistry; the relative binding affinities of these modified hormones with receptor to the oestradiol respect have been measured.
S. Top, A. Vessieres, J. Abjean and G. Jaouen, J. Chem. Soc., Chem. Commun., 1984, 428 DOI: 10.1039/C39840000428
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