Issue 7, 1984

Synthesis of hydrido–iridium(III) complexes from a trifluoromethanesulphonato intermediate

Abstract

The versatile new precursor to bis-2,2′-bipyridine complexes of IrIII, cis-[IrIII(bpy)2(OSO2CF3)2][CF3SO3](bpy = 2,2′-biyridine), has been isolated and used for the preparation of the new hydrido complexes of IrIII, cis-[Ir(bpy)2(PPh3)H][PF6]2 and cis-[Ir(bpy)2H2][PF6], and for an improved, high-yield synthesis of [Ir(bpy)3][PF6]3.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 403-405

Synthesis of hydrido–iridium(III) complexes from a trifluoromethanesulphonato intermediate

B. P. Sullivan and T. J. Meyer, J. Chem. Soc., Chem. Commun., 1984, 403 DOI: 10.1039/C39840000403

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements