SCHEDULED MAINTENANCE
Extensive ab initio calculations have yielded a detailed mechanism for Berry pseudorotation in PF5, for which a barrier of 16± 2 kj mol–1 is obtained, and a complete quadratic force field which gives an excellent account of observed vibrational frequencies.
C. J. Marsden, J. Chem. Soc., Chem. Commun., 1984, 401 DOI: 10.1039/C39840000401
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