Issue 5, 1984

Degradative insertion reactions of nido-7,9-C2B9H12.Synthesis and properties of 4-thia -6,8-dicarba-arachno-nonborane (10),4,6,8-SC2B6H10

Abstract

The reaction of 7,9-C2B9H12(1)with NaNO2and Na2SO3in dilute hydrochloric acid affords 6,8-C2B7H13(2)and the new thiacarbaborane 4,6,8-SC2B6H10(3)the structure of which is proposed on the basis of 1H and 11B n.m.r. spectra.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 299-300

Degradative insertion reactions of nido-7,9-C2B9H12.Synthesis and properties of 4-thia -6,8-dicarba-arachno-nonborane (10),4,6,8-SC2B6H10

K. Baše, S. Heřmánek and F. Hanousek, J. Chem. Soc., Chem. Commun., 1984, 299 DOI: 10.1039/C39840000299

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