Issue 4, 1984

Stereochemistry and mechanism of the nickel-catalysed hydrocyanation of conjugated dienes

Abstract

Nickel-catalysed addition of deuterium cyanide to cyclohedxa-1,3-diene was shown to occur with cis stereochemistry, indicating that a cis-migration of co-ordinated cyanide takes place in an intermediate π-allylnickel complex.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 260-261

Stereochemistry and mechanism of the nickel-catalysed hydrocyanation of conjugated dienes

Jan-E. Bäckvall and O. S. Andell, J. Chem. Soc., Chem. Commun., 1984, 260 DOI: 10.1039/C39840000260

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