Issue 4, 1984

Conversion of aliphatic and alicyclic carboxylic acids into nor-hydroperoxides, nor-alcohols, and nor-oxo derivatives using radical chemistry

Abstract

Radicals generated from esters of N-hydroxypyridine-2-thione react smoothly with oxygen in the presence of t-butyl thiol to furnish nor-hydroperoxides, from which the corresponding alcohols and carbonyl derivatives can be readily obtained.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 242-244

Conversion of aliphatic and alicyclic carboxylic acids into nor-hydroperoxides, nor-alcohols, and nor-oxo derivatives using radical chemistry

D. H. R. Barton, D. Crich and W. B. Motherwell, J. Chem. Soc., Chem. Commun., 1984, 242 DOI: 10.1039/C39840000242

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