Stereospecific pig liver esterase-catalysed hydrolysis of monocyclic meso-1,2-diesters provides a convenient preparative route to both enantiomers of useful chiral lactones and demonstrates a sharply defined and unprecedented ring-size-mediated reversal of stereospecificity.
G. Sabbioni, M. L. Shea and J. B. Jones, J. Chem. Soc., Chem. Commun., 1984, 236 DOI: 10.1039/C39840000236
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