Co-condensation of manganese or rhenium atoms with a mixture of benzene and trimethylphosphine forms the compounds Mn(η-C6H6)(PMe3)2H and [Re(η-C6H6)(PMe3)2]2 respectively; the latter gives rise to the derivatives Re(η-C6H6)(PMe3)2R (R = I or H).
M. L. H. Green, D. O'Hare and J. M. Wallis, J. Chem. Soc., Chem. Commun., 1984, 233 DOI: 10.1039/C39840000233
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