Issue 3, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

A novel alkynylation reaction of epoxy alcohols: use in the synthesis of erythro-6-acetoxyhexadecan-5-olide

Masahiko Yamaguchi  and  Ichiro Hirao  

Abstract

Lithium acetylides in the presence of BF3·Et2O react with epoxy alcohols derived from (E)-allylic alcohols to give erythro-1,2-diols, a reaction used successfully in the stereoselective synthesis of erythro-hexadecan-5-olide.

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Article information

DOI
https://doi.org/10.1039/C39840000202
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 202-203

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A novel alkynylation reaction of epoxy alcohols: use in the synthesis of erythro-6-acetoxyhexadecan-5-olide

M. Yamaguchi and I. Hirao, J. Chem. Soc., Chem. Commun., 1984, 202 DOI: 10.1039/C39840000202

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