SCHEDULED MAINTENANCE
Siloxyammonium salts prepared from tertiary amine N-oxides and trialkylsilyl trifluoromethanesulphonate undergo rearrangement in the presence of strong bases to give α-siloxyamines, which can be converted into secondary amine derivatives.
R. Okazaki and N. Tokitoh, J. Chem. Soc., Chem. Commun., 1984, 192 DOI: 10.1039/C39840000192
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