The currently accepted mechanism for decarboxylative transamination is shown to be incorrect; the intervention of 1,3-dipolar species in the decarboxylative transamination of α-amino acids is demonstrated by trapping with a range of dipolarophiles.
R. Grigg and S. Thianpatanagul, J. Chem. Soc., Chem. Commun., 1984, 180 DOI: 10.1039/C39840000180
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