Ab initio calculations including electron correlation show that the isomerizations of both H2Si![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2 to H![[S with combining umlaut]](https://www.rsc.org/images/entities/char_0053_0308.gif)
i–CH3 and CH3SiHCH2 to CH3–i–CH3 are almost thermonetral and proceed with a siazeable barrier of ca. 40 kcal/mol(ca. 167 kJ/mil); there is no signficant effect of metyl substitution.
S. Nagase and T. Kudo, J. Chem. Soc., Chem. Commun., 1984, 141 DOI: 10.1039/C39840000141
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...