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The reaction of β-stannyl acrylates with carbon redicals, generated from the corresponding bromides, to afford β-alkyl acrylates is the key carbon–carbon coupling step in a synthesis of the fungal dienyl isonitrile antibiotic (1).
J. E. Baldwin, D. R. Kelly and C. B. Ziegler, J. Chem. Soc., Chem. Commun., 1984, 133 DOI: 10.1039/C39840000133
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