Methylthio activating groups have been found to improve the yields in six different isoquinoline syntheses: in four cases the improvement was from zero, in the unactivated system, to between 54 and 94%.
M. R. Euerby and R. D. Waigh, J. Chem. Soc., Chem. Commun., 1984, 127 DOI: 10.1039/C39840000127
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