A novel approach to aminocyclitol analogues from azidotrideoxyhex-5-enopyranosides
Abstract
Application of the Ferrier's carbocyclic ring closure to methyl 3-azido-2,3,6-trideoxyhex-5-enopyranosides leads to cyclitol derivatives (3)and (5) suitable for the convenient synthesis of 1,3-diaminocyclitol -type aminoglycoside antibiotic analogues.
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