The tripod ligand, HC(PPh2)3, can be used to construct heterobimetallic complexes such as [(CO)5FeRh(tripod)]+, the X-ray structure of which shows the presence of a metal–metal bond.
A. A. Bahsoun, J. A. Osborn, P. H. Bird, D. Nucciarone and A. V. Peters, J. Chem. Soc., Chem. Commun., 1984, 72 DOI: 10.1039/C39840000072
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