Issue 1, 1984

The ‘bare’ Sn2+ ion. X-Ray crystal structure and Mössbauer spectrum of (Sn2+)-(SbF6)2(AsF3)2

Abstract

The 119Sn Mössbauer spectrum of the title compound shows the highest isomer shift, with no detectable quadrupole splitting, so far recorded for a tin(II) species and the crystal structure reveals a nine co-ordinate arrangement of fluorine atoms around the tin atom, with a distortion in geometry compatible with the presence of the lone pair of electrons.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 50-51

The ‘bare’ Sn2+ ion. X-Ray crystal structure and Mössbauer spectrum of (Sn2+)-(SbF6)2(AsF3)2

A. J. Edwards and K. I. Khallow, J. Chem. Soc., Chem. Commun., 1984, 50 DOI: 10.1039/C39840000050

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