Issue 1, 1984

Synthesis and X-ray crystal structure of 1,2,3-triphenylphosphirene

Abstract

1,2,3-Triphenylphosphirene is prepared from its P→W(CO)5 complex by a two step decomplexation procedure involving iodine and 1-methylimidazole; its X-ray crystal structure analysis shows a very strained ring (< CPC = 41.8°) with no electronic delocalization.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 45-46

Synthesis and X-ray crystal structure of 1,2,3-triphenylphosphirene

A. Marinetti, F. Mathey, J. Fischer and A. Mitschler, J. Chem. Soc., Chem. Commun., 1984, 45 DOI: 10.1039/C39840000045

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