1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes. A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans. Possible reaction mechanisms are also discussed.
A. De Renzi, A. Panunzi, A. Saporito and A. Vitagliano, J. Chem. Soc., Perkin Trans. 2, 1983, 993 DOI: 10.1039/P29830000993
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