Issue 0, 1983

A new synthetic approach to quassinoids via an intramolecular Diels-Alder reaction: a stereoselective construction of the klaineanone ring system

Abstract

Thermolysis of the benzocyclobutene derivative (25) prepared from norcamphor (6) gave stereoselectively the tetracyclic compound (27), which was converted into the D-deoxyquassinoid derivative (2) possessing the same ABCD-ring fusion as that of klaineanone (1).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 2569-2576

A new synthetic approach to quassinoids via an intramolecular Diels-Alder reaction: a stereoselective construction of the klaineanone ring system

K. Fukumoto, M. Chihiro, M. Ihara, T. Kametani and T. Honda, J. Chem. Soc., Perkin Trans. 1, 1983, 2569 DOI: 10.1039/P19830002569

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