Issue 0, 1983

Transformations of 4,9-dimethyl-2,3,7,8-tetra-azatetracyclo[7.3.1.0.4,1206,10]trideca-1,6-diene, a bishydrazone having two bridgehead double bonds

Abstract

Reduction of the anti-Bredt bishydrazone 4,9-dimethyl-2,3,7,8-tetra-azatetracyclo[7.3.1.0.4,1206,10]trideca-1,6-diene with lithium aluminium hydride–aluminium chloride or by catalytic hydrogenation gives the bishydrazine 1,6-dimethyl-2,3,7,8-tetra-azatetracyclo[7.3.1.0.4,1206,10]tridecane, but reaction with either lithium aluminium hydride or aluminium chloride gives dihydropyrazoles by ring cleavage.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 2545-2549

Transformations of 4,9-dimethyl-2,3,7,8-tetra-azatetracyclo[7.3.1.0.4,1206,10]trideca-1,6-diene, a bishydrazone having two bridgehead double bonds

J. M. Mellor and R. Pathirana, J. Chem. Soc., Perkin Trans. 1, 1983, 2545 DOI: 10.1039/P19830002545

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