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Issue 0, 1983
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Nitroxide radicals. Part 21. Spontaneous decomposition of N-aryl 1- and 2-naphthyl nitroxides

Abstract

N-Aryl 1-naphthyl nitroxides self-react in solution to give the corresponding secondary amines and N-aryl-1,4-naphthoquinone imines. When reaction at the 4-naphthyl position is hindered by substituents benzoquinone imines are also produced. N-Phenyl 2-naphthyl nitroxide under similar conditions gives the corresponding amine and 2-phenylamino-1,4-naphthoquinone via a 1,2-naphthoquinone imine N-oxide intermediate.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1983, 1759-1764
Article type
Paper

Nitroxide radicals. Part 21. Spontaneous decomposition of N-aryl 1- and 2-naphthyl nitroxides

A. R. Forrester, J. D. Fullerton and G. McConnachie, J. Chem. Soc., Perkin Trans. 1, 1983, 1759
DOI: 10.1039/P19830001759

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