Conversion of 1-benzyl-1-azaspiro[5.5]undec-7-en-9-one (7), readily available using simple organoiron chemistry, in six steps into (±)-depentylperhydrohistrionicotoxin (3) is reported. This compound has been previously reported as an intermediate for synthesis of (±)-perhydrohistrionicotoxin.
A. J. Pearson and P. Ham, J. Chem. Soc., Perkin Trans. 1, 1983, 1421 DOI: 10.1039/P19830001421
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