Jump to main content
Jump to site search

Issue 0, 1983
Previous Article Next Article

Ozonolysis of cis- and trans-1,4-dichlorobut-2-ene. Non-concerted formation of primary ozonides

Abstract

The ozonolysis of cis- or trans-CH2Cl·CH[double bond, length half m-dash]CH·CH2Cl (1) performed at –10 °C in a participating solvent (CD3OD) has been found to lead to non-concerted formation of primary ozonides (9). The heterolysis of these unusually stable primary ozonides to the corresponding alkoxy peroxide (11) and aldehyde (12) was monitored and the data have been tentatively rationalized by assuming neighbouring halogen participation which actually increases the stability of the Criegee zwitterionic intermediate (6).

Back to tab navigation

Article type: Paper
DOI: 10.1039/P19830001319
J. Chem. Soc., Perkin Trans. 1, 1983, 1319-1323

  •   Request permissions

    Ozonolysis of cis- and trans-1,4-dichlorobut-2-ene. Non-concerted formation of primary ozonides

    E. Tempesti, M. Fornaroli, L. Giuffre, E. Montoneri and G. Airoldi, J. Chem. Soc., Perkin Trans. 1, 1983, 1319
    DOI: 10.1039/P19830001319

Search articles by author

Spotlight

Advertisements