An explanation for the racemic modification is put forward using computer simulation to quantify the statistical correlation between a molecule's centre-of-mass translational velocity and its own angular momentum when immersed in an ensemble of like or mirror-image enantiomers. It is illustrated with bromochlorofluoromethane and t-1,2-dimethylcyclopropane.
M. W. Evans, J. Chem. Soc., Faraday Trans. 2, 1983, 79, 1811 DOI: 10.1039/F29837901811
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