The rate of reaction between hexacyanoferrate(III) and iodide ions has been measured in several aqueous concentrated salt solutions and in several isodielectric water–cosolvent mixtures. The results are not in agreement with the predictions of the Olson–Simonson model, but can be rationalized as a consequence of the salt–water and cosolvent–water interactions.
P. P. Tejeda, J. R. Velasco and F. S. Burgos, J. Chem. Soc., Dalton Trans., 1983, 2679 DOI: 10.1039/DT9830002679
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