Issue 8, 1983

Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III)

Abstract

The first-order rate constants for the replacement of X from 21 different complexes of the type trans-[ML(A)X]n+[M = CoIII, RuIII, or RuII; L = either two bidentate or one quadridentate amine ligand; and (A)X =(Cl)Cl, (Cl)Br, (Br)Cl, or (Br)Br] have been determined over a range of temperature. It has been found that the ruthenium(II)(d6) complexes behave much more like the corresponding ruthenium(III)(d5) than the cobalt(III)(d6) and rhodium(III)(d6) systems.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1983, 1641-1645

Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III)

C. Poon, T. Lau, C. Wong and Y. Kan, J. Chem. Soc., Dalton Trans., 1983, 1641 DOI: 10.1039/DT9830001641

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements