Pyrazine is shown to form complexes [Zn(pyz)2X2](pyz = pyrazine, X = Cl or Br) as well as the previously known [Zn(pyz)X2]. E.s.r. spectra of these compounds doped with manganese(II) ions show the stereochemistry to be polymeric with pyrazine bridges, and the doping technique permits identification of the complexes even in mixtures.
R. B. Birdy and M. Goodgame, J. Chem. Soc., Dalton Trans., 1983, 1469 DOI: 10.1039/DT9830001469
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