Issue 7, 1983

Manganese(II) ions as stereochemical probes in reactions of zinc halides with pyrazine

Abstract

Pyrazine is shown to form complexes [Zn(pyz)2X2](pyz = pyrazine, X = Cl or Br) as well as the previously known [Zn(pyz)X2]. E.s.r. spectra of these compounds doped with manganese(II) ions show the stereochemistry to be polymeric with pyrazine bridges, and the doping technique permits identification of the complexes even in mixtures.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1983, 1469-1471

Manganese(II) ions as stereochemical probes in reactions of zinc halides with pyrazine

R. B. Birdy and M. Goodgame, J. Chem. Soc., Dalton Trans., 1983, 1469 DOI: 10.1039/DT9830001469

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