Issue 7, 1983

Partially oxidised tetracyanoplatinate complexes containing both divalent and monovalent cations

Abstract

A series of new one-dimensional metals based on partially oxidised tetracyanoplatinate complexes containing both monovalent and divalent cations is described. The complexes appear to be isostructural with K2[Pt(CN)4]Cl0.3·3H2O but with ca. 13% of the cation sites containing a divalent cation and with all the halide sites occupied. The small change in composition is shown to have a large effect on the electrical conduction properties of the compounds because the effect of the introduction of divalent cations results in an increased stiffness of the lattice. This leads to a reduction of λ, the electron phonon coupling constant, resulting in increased conductivity at low temperatures.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1983, 1411-1415

Partially oxidised tetracyanoplatinate complexes containing both divalent and monovalent cations

G. S. V. Coles, A. E. Underhill and K. Carneiro, J. Chem. Soc., Dalton Trans., 1983, 1411 DOI: 10.1039/DT9830001411

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