η-Arenetungsten chemistry: η-allyl, η-butadiene, tertiary phosphine, and hydrido derivatives
Abstract
The syntheses and properties of the new η-arenetungsten compounds [{W(η-C6H5Me)(η-C3H5)Cl}2], [W(η-C6H5Me)(η-C3H5)(OCOMe)], [W(η-C6H5Me)(η-C3H5)(OCOPh)], [W(η-C6H5Me)(η-C3H5)(PPhMe2)Cl], [W(η-C6H5Me)(η-C3H5)(PR2CH2CH2PR2)]PF6(R = Me or Ph), [W(η-C6H5Me)(η-C3H5)(η-C4H6)]PF6, [W(η-C6H5Me)(η-C3H5)(MeCN)2]PF6, [W(η-C6H5Me)(PMe3)2Cl2H]PF6, [W(η-C6H5Me)(Me2PCH2CH2PMe2)H2], and [W(η-C6H5Me)(Me2PCH2CH2PMe2)H3]BF4 are described.