Electrolysis of dimethylmagnesium in tetrahydrofuran (thf) with a gallium anode yields the adduct GaMe3·thf directly; the trialkylamine and trialkylphosphine adducts GaMe3·L (L = NEt3, PMe3, or PEt3) are obtained by direct addition of an excess of L to GaMe3·thf. Free GaMe3 is obtained by reaction of Mel with a Mg–Ga alloy in an ether solvent.
A. C. Jones, D. J. Cole-Hamilton, A. K. Holliday and M. M. Ahmad, J. Chem. Soc., Dalton Trans., 1983, 1047 DOI: 10.1039/DT9830001047
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