The 127I Mössbauer spectra of a number of iodine(III) cations and related molecules having four ligands and two non-bonding electron pairs about the central iodine have been recorded at 4.2 K. The Mössbauer parameters are dominated by the primary bonds to the iodine which are largely of p character.
T. Birchall and R. D. Myers, J. Chem. Soc., Dalton Trans., 1983, 885 DOI: 10.1039/DT9830000885
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