The matrix i.r. spectra obtained from the vaporisation of samples of potassium, rubidium, and caesium arsenate show characteristic bands due to the species MAsO2 and new features which are assigned to molecular arsenates MAsO3. For CsAsO3, fundamentals are assigned at 978.2, 923.4, 880.0, 368, and 335 cm–1, and 18O enrichment experiments indicate a C2v bidentate structure.
J. S. Ogden, T. J. Sibley and S. J. William, J. Chem. Soc., Dalton Trans., 1983, 851 DOI: 10.1039/DT9830000851
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...