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Issue 2, 1983
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One-electron cyclic voltammetric reduction potentials of some molybdo-oxaziridines

Abstract

The electrochemistry of [MoO(S2CNEt2)2(ONC6H4X-p)](X = CH3, H, or Cl) has been examined voltammetrically. A one-electron cyclic voltammetric reduction peak (Epc) observed near –1.2 V (versus a saturated calomel electrode) is assigned to the process MoVI MoV. The MoV species is too unstable for electrochemical detection. The Epc values correlate linearly with Hammett parameters of the substituent X. The reduction peak of [MoO2(S2CNEt2)2] occurs at –1.03 V. The oxaziridine group is found to be a better donor than the oxo-group.

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Article information


J. Chem. Soc., Dalton Trans., 1983, 401-403
Article type
Paper

One-electron cyclic voltammetric reduction potentials of some molybdo-oxaziridines

P. Ghosh, P. Bandyopadhyay and A. Chakravorty, J. Chem. Soc., Dalton Trans., 1983, 401
DOI: 10.1039/DT9830000401

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