The potentiometric titration technique has been used to study the hydrolytic behaviour of the scandium(III) ion in 0.10 mol dm–3 potassium nitrate at 25 °C. Data treatment indicates the presence of the species [Sc(OH)]2+, [Sc2(OH)2]4+, and [Sc3(OH)5]4+, the –log βpq values being 4.840 (0.008), 6.096 (0.004), and 17.567 (0.006) respectively; the estimated standard deviations are given in parentheses.
P. L. Brown, J. Ellis and R. N. Sylva, J. Chem. Soc., Dalton Trans., 1983, 35 DOI: 10.1039/DT9830000035
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