In complete agreement with experimental results ab initio molecular orbital calculations predict that ionized hydroxy(methyl)carbene, [CH3COH]+, does not only exist as a stable C2H4O˙+ isomer but also serves as the key intermediate in the isomerization–dissociation processes of the cation radical of gaseous vinyl alcohol.
Y. Apeloig, M. Karni, B. Ciommer, G. Depke, G. Frenking, S. Meyn, J. Schmidt and H. Schwarz, J. Chem. Soc., Chem. Commun., 1983, 1497 DOI: 10.1039/C39830001497
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