The reaction of bis(cyclopentadienyl)titanium dicarbonyl with tetrasulphur tetranitride yields cp2 TiS3N4(cp = cyclopentadienyl); X-ray crystallographic analysis of this compound reveals it to be based on an eight-membered TiS3N4 ring.
C. G. Marcellus, R. T. Oakley, A. W. Cordes and W. T. Pennington, J. Chem. Soc., Chem. Commun., 1983, 1451 DOI: 10.1039/C39830001451
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