The neutral gold cluster, Au3, has been trapped in a benzene matrix at 77 K and its e.s.r. spectrum observed: it consists of sixteen sets of quartets with a197(2)= 382.9 G (3.83 × 10–2 T), a197(1)= 58.0 G (5.8 × 10–3 T), and g= 1.865; these parameters suggest a slightly bent structure with 2B2(C2v) ground state.
J. A. Howard, R. Sutcliffe and B. Mile, J. Chem. Soc., Chem. Commun., 1983, 1449 DOI: 10.1039/C39830001449
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