A-Ring [13C]-labelled averufin has been synthesized and found to be incorporated intact into aflatoxin, B1, where the labelling pattern in the fused cyclopentenone unequivocally establishes the origin of the carbon backbone as consistent with current biogenetic theories.
C. A. Townsend and S. G. Davis, J. Chem. Soc., Chem. Commun., 1983, 1420 DOI: 10.1039/C39830001420
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