Issue 23, 1983

Platinum(I) dimer chemistry: distortion of co-ordination geometry in [Pt2Br2(µ-CO)(PPh3)3]

Abstract

X-Ray crystal structure determination and spectroscopic measurements on the title compound show it to have an asymmetrically bridging CO ligand which is believed to lead to some valence disproportion in contrast to its precursor [Pt2Br4(CO)2]2–.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1386-1388

Platinum(I) dimer chemistry: distortion of co-ordination geometry in [Pt2Br2(µ-CO)(PPh3)3]

R. J. Goodfellow, I. R. Herbert and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1983, 1386 DOI: 10.1039/C39830001386

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