The tetrasubstituted prochiral amido-alkenes (1a, b), (2a, b), and (3b) have been homogeneously hydrogenated under very mild conditions by iridium complexes of the type [Ir(cod)(bzn)(L)][ClO4](cod = cyclo-octa-1,5-diene, bzn = benzonitrile, L = tricyclohexylphosphine or neomenthyldiphenylphosphine).
L. A. Oro, J. A. Cabeza, C. Cativiela, M. D. D. de Villegas and E. Meléndez, J. Chem. Soc., Chem. Commun., 1983, 1383 DOI: 10.1039/C39830001383
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