The radical cations of norbornane and norbornadiene have been generated radiolytically in Freon matrices at 4.2 K; the unpaired electron orbitals of these cations were identified as the 4a2σcc and 6b2πcc orbital, respectively.
K. Toriyama, K. Nunome and M. Iwasaki, J. Chem. Soc., Chem. Commun., 1983, 1346 DOI: 10.1039/C39830001346
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